Tổng hợp và nghiên cứu tính chất của các phức chất niken(II), paladi(II) dipivaloylmetan

Abstract

The complexes of nickel(II) and palladium(II) with dipivaloylmethane (DPM: 2,2,6,6- tetramethyl-3,5-heptandion) were synthesized. The experimental results showed that the formula of the complex of nickel(II) with DPM formed in diethylether - ethanol(EtOH) solvent was Ni(DPM)₂.EtOH. This complex was converted into Ni(DPM)₂ complex by heating at 80°C. The formula of Pd(II) - DPM complex was Pd(DPM)₂. Both of Pd(DPM)₂ and Ni(DPM)₂ were good volatile complexes. Journal of Chemistry, T. 42 (1), Tr. 83 - 87, 2004 The full text of this article is available in Vietnamese.