Synthesis Co-B/Al-MCM-41 with the change of Al/Si ratios for ethylene hydropolymerization

Authors

  • Truong Quoc Hung
  • Phan Long Nhat
  • Le Thi Tu
  • Dao Quoc Tuy

Abstract

In the research, catalyst activity  of Al-MCM-41  with different  ratios of Al/Si are compared by observing catalyst samples that successfully synthesized. The ratio 30 of Al/Si was selected for impregnation process  with Co to obtain the formation of 5.0% Co/Al-MCM-41, 7.5% Co/Al-MCM-41, 10% Co/Al-MCM-41, 15% Co/Al-MCM-41 and15% Co/Al-MCM-41. Through experiments, 10% Co/Al-MCM-41 sample was advisable to added with B. for evaluation of metal dispersion on carrier surface. Liquid fuel products were obtained by using . 10% Co-0.6% B/Al-MCM-41 catalyst. Hydropolymerization of ethylene under low temperature (190°C) and normal pressure (1atm) was clearly accelerated by 10% Co-0.6% B/Al-MCM-41. This would be a positive sign for fuel industry to convert ethylene, CO and H2  into valuable products.

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References

Minh. N.Q, Tuy. D.Q, Vietnam Journal of Catalysis and Adsorption 7 2 (2018) 128.

Minh. N.Q, Hung. B.Q, Tuy. D.Q, Journal Of Chemistry 55 2 (2017) 115-118.

Ya. T. Eidus, Hoang Trong Yem, N. I. Ershov, Institute of Organic Chemistry, Academy of Sciences of the USSR, Moscow (1974).

Hung. T.Q, Minh. N.Q, Tuy. D.Q , Vietnam Journal of Catalysis and Adsorption (2019) 79-85.

Hung. T.Q, Nhat. P.L, Tuy. D.Q, Vietnam Journal of Catalysis and Adsorption (2020) 107-113. https://doi.org/10.51316/jca.2020.037

Nguyễn Văn Bằng, Tạp chí Hóa học 50 1 (2012) 9 - 13. https://doi.org/10.15625/2013

M. Jaroniec, J. Choma, and M. Kruk, Studies in Surface Science and Catalysis 128 (2000) 225-234.

J. Panpranot, J. G. Goodwin, Jr, A. Sayari, J. Catal, 211 (2002) 530 - 539. https://doi.org/10.1007/s11244-015-0436-3

N. Cuello, V. Elías, M. Crivello, M. Oliva, G. Eimer, Journal of Solid State Chemistry, 205 (2013) 91 – 96. https://doi.org/10.1016/j.jssc.2013.06.028

L. Obalová, K. Karásková, K. Jirátová, F. Kovanda, Applied Catalysis B: Environmental 90 1-2 (2009), 132-140. https://doi.org/10.1016/j.apcatb.2009.03.002

M. Simionato, E. M. Assaf, Catalysts Materials Research 6 4 (2003) 535-539. https://doi.org/10.1590/S1516-14392003000400019

J. Wang, Q. Liu, Solid states communications 148 11-12 (2008) 529-533. https://doi.org/10.1016/j.ssc.2008.09.052

L. Qiang, L. Wen-zhi, Z. Dong, Z. Xi-feng, University of Science and Technology of China, No. 96 Jinzhai Road, Anhui, Hefei 230026, China. https://doi.org/10.1016/j.jaap.2009.01.002

S. Weiming, L. Xing, J. Tao and D. Qigang, Chinese Journal of Chemical Engineering 20 5 (2012) 900 - 905. https://doi.org/10.1016/S1004-9541(12)60416-9

P. Kowalczyk, M. Jaroniec, Artur P. Terzyk, K. Kaneko and, Duong D. Do Langmuir 21 5 (2005) 1827-1833. https://doi.org/10.1021/la047645n

S. Lim, D. Ciuparu, Y. Chen, Y. Yang, L. Pfefferle, and, Gary L. Haller, The Journal of Physical Chemistry B 109 6 (2005) 2285-2294. https://doi.org/10.1021/jp048881

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Published

30-07-2022