Evaluation of nitrate removal efficiency from aqueous solutions using modified biochar derived from coffee husk

Authors

  • Le Hong Minh Institute of Materials, Biology and Environment/Academy of Military Science and Technology
  • Vu Ngoc Toan Institute of Materials, Biology and Environment/Academy of Military Science and Technology
  • Nguyen Thi Thu Huong Institute of Materials, Biology and Environment/Academy of Military Science and Technology
  • To Phuong Linh Institute of Materials, Biology and Environment/Academy of Military Science and Technology
  • Le Thuy Trang Institute of Materials, Biology and Environment/Academy of Military Science and Technology
  • Le Xuan Dong Department of Military Science, Ministry of National Defense
  • Dang Thi Ngoc Chau Department of Military Science, Ministry of National Defense

Keywords:

Adsorption; Biochar; Coffee husk; Nitrate (NO₃⁻)-

Abstract

This study presents the fabrication and evaluation of the nitrate adsorption capacity of modified biochar derived from coffee husk. The coffee husks were initially pyrolyzed at 350 °C for 1 hour, then soaked in 1 M KOH solution for 24 hours, followed by a second pyrolysis step at 700 °C for 2 hours. The resulting biochar was characterized using FT-IR, BET, and SEM techniques, and its nitrate removal efficiency from aqueous solutions was investigated. The highest nitrate removal efficiency (82,38%) was achieved under the following conditions: pH 3, biochar dosage of 1,5 g/100 mL, nitrate concentration of 50 mg/L, and reaction time of 210 minutes. The pseudo-first-order kinetic model and the Langmuir isotherm model were applied to describe the adsorption behavior, showing good agreement with the experimental data.

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Published

2025-08-25

Issue

Section

Chemistry, Biology & Environment